Abstract
Metastable states of the [Ru(NO)Cl 5] 2− ion were investigated in the framework of density functional theory. Calculations were carried out with B3LYP and SVWN functionals using the LanL2DZ and DZVP basis sets. Three local minima corresponding to the linear η 1-NO, η 1-ON, and side-wise η 2-NO coordination were found. Synchronous transit-guided reaction path calculations show that these local minima belong to the same potential energy surface. The change of the RuNO angle along the reaction coordinate is accompanied by out-of-plane distortion of the O–N–Ru–Cl trans fragment in the vicinity of the transition states.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.