Abstract

Using lattice gas Monte Carlo simulations, we studied the dewetting transition of water confined between a spherical tip and a plate, which is relevant to atomic force microscopy measurements conducted in water. The dewetting transition was investigated by varying the tip-plate distance, tip size, and the pressure of water. With introduction of an atomic scale roughness (1 < nm) in the tip and the plate, the dewetting transition significantly increased in range and yielded an enhanced hydrophobic force between the tip and the plate. This finding is in agreement with the experimental results previously reported by Singh et al.

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