Abstract
Infrared spectra of Dewar pyridine, produced from pyridine in an argon matrix by UV irradiation, have been measured by matrix-isolation infrared spectroscopy. Vibrational assignments have been performed with an aid of the DFT calculation, where the 6-31++G ** basis set was used to optimize the geometrical structures. It has also been found that cyclobutadiene and HCN are produced by further photolysis of Dewar pyridine as well as by direct photodissociation of pyridine. The relative rate constants are estimated from the infrared intensity changes upon UV irradiation.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Photochemistry and Photobiology A: Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
