Abstract
TiO2 is one of the most promising photocatalyst with excellent efficiency and stability in photocatalytic reaction. However, TiO2 can only be activated under UV light irradiation because of the wide band gap. Recently, several metal ions surface modified TiO2 (M–TiO2) has been developed as a visible light sensitive photocatalysis1. Visible light irradiation initiates effective charge transfer between metal ions and TiO2.Here, we report novel visible light driven photocatalyst (B12−M−TiO2) composed of the vitamin B12 derivatives which is unique cobalt complex and several M–TiO2 and introduce visible light-induced green molecular transformations mediated by B12-M-TiO2 2.Reference[1] M. Okazaki, Y. Wang, T. Yokoi, K. Maeda, J. Phys. Chem. C, 2019, 123, 10429.[2] K. Shichijo, M. Fujitsuka, Y. Hisaeda, H. Shimakoshi, J. Organomet. Chem., 2020, 907, 121058. Figure 1
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