Development of novel network structures in crosslinked liquid-crystalline polymers

Abstract

Crosslinked liquid-crystalline polymers (CLCPs) show macroscopic deformation along with a change in molecular order, which is triggered by various stimuli such as heat, electricity, and light. CLCPs containing photochromic moieties are realizable as photoresponsive soft actuators. This review focuses on recent developments in novel network structures of CLCPs: rearrangeable networks and interpenetrating polymer networks (IPNs). CLCPs with dynamic covalent bonds could be reshaped into 3D architectures through the rearrangement of the network topology, in contrast with conventional crosslinked polymers memorizing permanent shapes. The reshaped samples showed various photoinduced motions depending on their initial shapes. Furthermore, amorphous polymers were incorporated into conventional CLCP networks to control mechanical and photoresponsive properties. The sequential formation of CLCP and amorphous polymer networks resulted in IPN films with a homogeneous alignment of mesogens. The elastic moduli of IPN films were controlled through the selection of amorphous components. The incorporation of soft components such as poly(dodecyl methacrylate) and poly(dimethylsiloxane) (PDMS) significantly enhanced the rate of photoinduced bending. These strategies of controlling the network structures of CLCPs could enable the versatile design of photomobile polymer materials as soft actuators with desired architectures and functions. Novel network structures were applied to crosslinked liquid-crystalline polymers (CLCPs) with photomechanical effects to enhance their performance and function. CLCPs with rearrangeable networks could be reshaped into 3D architectures, in contrast with conventional crosslinked polymers memorizing permanent shapes. The reshaped samples showed various photoinduced motions depending on their initial shapes. Furthermore, interpenetrating polymer networks (IPNs) were developed to improve mechanical and photoresponsive properties of CLCPs. These strategies of controlling the network structures of CLCPs could enable the versatile design of photomobile polymer materials as soft actuators.