Abstract

In this work, we developed a thin-film anion-conducting electrolyte composed of NaCo2O4. The NaCo2O4 powder was slurried with poly vinylidene difluoride (PVDF) and N-methyl pyrrolidone (NMP). The slurry was painted on the punched metal base or meshed metal base by the doctor blade method, followed by calcination at 600{degree sign}C for 5 h. In making NaCo2O4 film, the shape of the base greatly affected the cell performance. The cell consisting of a thin-film electrolyte on punched base showed higher performance than that on meshed base, since meshed base is difficult to be packed densely with NaCo2O4 slurry.

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