Abstract
Development of PDAs has received great attention in many fields due to their optical and chromatic properties towards external stimuli. In this article, two novel PDAs (NPI-PDA1 and NPI-PDA2) containing naphthalimide as a head group are designed and synthesized through self-assembly followed by topochemical polymerization, and these compounds show a reversible green-to-red colorimetric transition upon heating. PEO-embedded films are fabricated to facilitate the investigation of the thermochromic properties, and the surface morphologies of the films are observed by SEM analysis. The thermochromic behavior and color transitions are observed using photography and electronic absorption spectroscopy. The changes in the extended ene-yne conjugated system of the polymer during heat treatment are successfully monitored by Raman spectrometry. Moreover, PDA-embedded crayon wax-based hand-writable pens are fabricated and used efficiently on a solid substrate. NPI-PDA1 and NPI-PDA2 display excellent reversibility in the temperature ranges of 25–120 °C and 25–160 °C, respectively in the PEO polymer and paraffin wax matrices.
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