Development of Mg-oxide–Ni hydrogen-storage alloys by reactive mechanical grinding

Abstract

Mg-oxide and Mg-oxide–Ni hydrogen storage alloys were prepared by mechanical grinding under H 2 (reactive mechanical grinding). Among these alloys, Mg – ( 7.5 wt % Fe 2 O 3 , 7.5 wt%Ni) prepared by grinding for 4 h with nano-structured Fe 2 O 3 particles and Ni showed the best hydrogen storage properties. The as-milled sample absorbed 4.75 wt% H at 593 K under 12 bar H 2 for 60 min. Its activation was accomplished after two hydriding–dehydriding cycles. The activated sample absorbed 4.36 wt% H at 593 K under 12 bar H 2 for 60 min and desorbed 4.26 wt% H at 593 K under 1.0 bar H 2 for 60 min. After hydriding–dehydriding cycling, Mg 2 Ni , Fe and MgO are formed. The large bar-like hydrided particles have round and expanding surfaces, suggesting that they expanded during the hydriding reaction, while the dehydrided particles exhibit contracted surfaces with wrinkles.