Development of highly efficient magnetically recyclable Cu2+/Cu0 nano-photocatalyst and its enhanced catalytic performance for the degradation of organic contaminations

Abstract

This work reports the successful functionalization of l-proline on the surface of superparamagnetic iron oxide nanoparticles (SPION) synthesized via a simple, cost-effective hydrothermal method. Moreover, the chemical attachment of Cu2+/Cu0 nanoparticles on the surface of SPION@l-proline was done by an in-situ deposition method. The developed nano-photocatalyst was characterized in detail by XRD, FT-IR, XPS, FE-SEM, TEM, EDX, BET, TGA, and VSM. XRD of SPION@l-proline-Cu reveals peaks of both SPION and copper nanoparticles which confirms the formation of nanophotocatalyst. TGA demonstrates a major weight loss between 250 and 310 °C due to l-proline which ensures the successful immobilization of SPION on the surface of l-proline. The band energy at 932 eV suggests a complete reduction of Cu2+ ion to Cu0 metal on the surface of SPION@l-proline nanocomposite as confirmed by the XPS technique. Under UV light irradiation, the photocatalytic reduction performance of the developed Cu2+ metal ion-based and Cu0 nanoparticle-based magnetic nano-photocatalysts was demonstrated and compared for the first time for the photocatalytic reduction of 4-NP, 4-NA, NB, MO, MB, and CR. The results show that Cu0-based magnetic nanophotocatalyst has slightly enhanced catalytic activity. Furthermore, solar-driven photocatalytic degradation of CR azo dye by synthesized nano-photocatalyst was also investigated, with a 95 % degradation efficiency in just 40 min. The developed magnetic nano-photocatalyst can easily be separated by using an external magnet due to the superparamagnetic nature of core material (SPION) at room temperature as confirmed from VSM and can be reused for multiple cycles without losing considerable catalytic activity. Because of its high photocatalytic efficiency, cost-effectiveness, good magnetic separation performance, non-toxicity, and strong thermal and chemical stabilities, Cu2+/Cu0-based magnetic nano-photocatalyst has potential application in wastewater treatment.