Development of H2 selective silica membranes: Performance evaluation through single gas permeation and gas separation tests

Abstract

To prove the usefulness and achieve penetration of microporous ceramic membranes in gas separation applications of industrial interest, their behavior needs to be validated and predicted at relatively realistic conditions. In this respect, the present study employed hybrid silica (HybSi) membranes, modified by chemical vapor infiltration (CVI) in order to render them more selective to hydrogen in hydrogen/carbon dioxide binary mixtures, which are representative to effluent streams of methane or biogas steam reforming/water gas shift processes. Experimental studies with a single modified membrane exhibited high hydrogen permeance (1.5.10−7 mol.m−2.s−1.Pa−1, at 250 °C) and H2/CO2 permselectivity (H2/CO2 = 61.3, at 250 °C). Gas separation tests with binary gas mixtures revealed that high hydrogen purity values (>99%) can be reached at different process conditions. The mathematical model, also developed in this study in order to interpret the experimental results, can reliably predict hydrogen separation process performance over a wide range of operating conditions and also serve as a tool for subsequent optimum process engineering purposes.