Development of fluorosilicon bivalve isocyanate microcapsules for multifunctional coatings with excellent self-repairing properties, enhanced hydrophobicity, and corrosion protection properties

Abstract

This study first self-made TMP-IPDI tetramer, and then prepared a fluorine-modified silicon dioxide double shell isocyanate type self-healing microcapsule (CBS-X/TMP-IPDI@PU@F-SiO2) using TMP-IPDI tetramer, fluorescent agent 4,4-bis (2-disulfonic acid sodium styrene) biphenyl (CBS-X) as the core material, polyurethane (PU) as the single shell, and fluorine modified silicon dioxide (F-SiO2) as the double shell using interfacial polymerisation method. Then, it was added to waterborne polyurethane (WPU) to prepare self-healing coatings and coatings. The chemical structure, microstructure, self-healing self detection, and mechanical properties of TMP-IPDI, CBS-X/TMP-IPDI@PU@F-SiO2, and composite coatings were characterized by infrared spectroscopy (FTIR), proton nuclear magnetic resonance (1H NMR), scanning electron microscopy (SEM), particle size analysis (PSA), X-ray electron spectroscopy (XPS) analysis, contact angle testing, tensile testing, electrochemical impedance testing, and Ultraviolet photograph. The results showed that the TMP-IPDI tetramer was successfully prepared. The average particle size of CBS-X/TMP-IPDI@PU@F-SiO2 prepared is 29 μm. The contact angle, tensile strength, low-frequency impedance and Nyquist curve radius of the repaired spots increased with the increase of the amount of CBS-X/TMP-IPDI@PU@F-SiO2 in WPUs; the increasing trend slowed down when the amount of CBS-X/TMP-IPDI@PU@F-SiO2 was >5 %. When the CBS-X/TMP-IPDI@PU@F-SiO2 dosage is 5 %, the WPU coating has good self-repair and self-detection performance. The stress before and after repair were 12.89 MPa and 20.11 MPa, respectively, with a repair rate of 80.3 %. The contact angle at the repair site can reach 100.8°, and the coating has good corrosion resistance. The microcapsules prepared based on fluorine-modified silica (F-SiO2) as the wall material have good self-healing performance for WPU coatings, achieving secondary protection of the repaired material.