Development of Fe0 biochar composites synergistically activated with MgFe2O4 and Fe2+ through one-step pyrolyzing Fe sludge and MgCl2 for enhanced aqueous Cr(VI) removal

Abstract

The surface passivation layer on Fe0 severely restricts its reactivity during environmental decontamination. In this study, a new composite—an Fe0 biochar composite (Fe0/BC) coupled with MgFe2O4 and Fe2+—was first developed for enhanced Cr(VI) removal by simple co-pyrolysis of Fe sludge (FS) with MgCl2. The characterization results demonstrated that MgFe2O4 and Fe0 could be formed simultaneously at 700 ℃. However, MgFe2O4 disappeared at temperatures of 800 and 900 ℃. By varying the flow rate of N2 and holding time, Fe0/BC was further optimized based on the determined MgCl2 to FS mass ratio (1.9:10.0) and temperature (700 °C). The optimal Fe0/BC (MBC700120-400–30) achieved a Cr(VI) removal efficiency of 97.67%, which was 2.43 times higher than that of the unmodified Fe0/BC obtained at 700 ℃. This enhanced reactivity was directly related to the electron transfer of Fe0 stimulated by MgFe2O4 as well as the conversion of passive corrosion products into Fe3O4 facilitated by soluble Fe2+ components. The predicted maximum adsorption capacity of MBC700120-400–30 was 85.43 mg/g (pH = 5) and the removal of Cr(VI) was dominated by chemisorption. The reduction of Cr(VI) to Cr(Ⅲ) was identified as the principal removal mechanism. Overall, this study demonstrates a novel strategy for developing functional Fe0-based materials for water contamination treatment.