Abstract

Abstract The iron concentration in natural water of acid sulfate soils is usually determined by complicated methods of SMEWW 3111B:2017 or ISO 6332: 1988 E in the laboratory for acidified water samples at pH ∼2–3. Therefore, the rapid field determination of iron content in natural water is a very useful method because it limits the error and reduces the experimental time for analysis. In this study, we proposed, developed, and tested a rapid colorimetric analysis method based on the chemical reaction of ferric and anion thiocyanate (SCN−) ions for an iron concentration range of 0–100 mg/L with a linear equation of ΔE = 0.5955x + 2.0909 and high correlation coefficient (R2) of 0.9864. The results from 10 water samples by this method were very close to those by flame absorption spectroscopy with a difference of less than 5%. Besides the biggest advantage of rapid site testing, this method also gives quite high accuracy compared to the molecular absorption method of ISO 6332:1988 E. In addition, this new method can quantify Fe3+, Fe2+, and total iron in water, suggesting a very useful and potential method for determining the iron content of natural water from acid sulfate soils.

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