Development of environmentally-friendly modified bioadsorbents for water treatment

Abstract

As a result of scientific research, it was found that synthesized pure sorbents based on a composite of Fe3O4 nanoparticles and AlgBT have an increased adsorption capacity due to the inclusion of double hydroxides and an alginate matrix. The processes of complex formation occur according to the principle of maximum inheritance of the structural features of the original coordination compounds, which make it possible to predict and implement the hypothetical structures of new compounds. All this significantly improves the adsorption capacity of the developed adsorbents with respect to phosphate ions. Modified sorbents with a clay basis are therefore a particularly intriguing field. The current research constructed and described modified sorbents, and then conducted tests in the laboratory to determine how well they absorbed phosphate. This study used spectroscopic techniques (SEM, FTIR, X-ray diffraction, and XRD analytical methods) to examine the structure and physicochemical characteristics of improved ecologically friendly sorbents based on alginates, bentonite, and nanoparticles. The alginate core may be physically and chemically modified and can take part in a variety of phosphate anion adsorption methods thanks to the active COOH and OH groups that are present there. The sorption efficiency was established for a modified Fe3O4NPs@AlgBT. Equilibrium in the system sorbent-an aqueous solution of Na2HPO4 is established in 10 hours after the start of sorption, while two-thirds of all sobbed anions pass into the solid phase during the first two hours. The limiting sorption of phosphate ions on modified Fe3O4NPs@AlgBT reaches 410 mg/g, which makes it possible to offer it as an effective sorbent for industrial wastewater treatment