Abstract
Li2S-2H3BO3: xCoN2O6.6H2O (x = 3, 4 and 5mol %) glass system was prepared. The microstructure and physical properties of glasses were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-Vis spectrophotometer and vibrating sample magnetometer (VSM). In order to measure the electrochemical properties of glasses, the cycling voltammograms (CVs) was employed where the highest specific capacitances of 97.972 mV/s was obtained from x= 5mol%. For structure-function of glasses, the S and Co oxidation states at S K-edge and Co K-edge and local structure around Co ions were studied by X-ray absorption spectroscopy (XAS) including X-ray absorption near edge structure (XANES) and extended X-ray absorption spectroscopy (EXAFS). It was found that, the S6+ oxidation state and mixing Co2+/3+ were revealed, respectively. Moreover, the Co K-edge EXAFS fitting was exhibited co-existence of CoA-O bond (tetrahedral coordination) and CoB-O bond (octahedral coordination) in all fabricated glasses with a difference proportional site.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
