Abstract
Cationic gallium phthalocyanine (RPcGa+) catalysts with SbF6– and Sb2F11–/Sb3F16– weakly coordinating anions were developed and used in the catalytic chemistry of donor-acceptor (D–A) cyclopropanes and related substrates. For the first time, these processes were implemented on the examples of [3 + 2]-cycloaddition/annulation reactions of D–A cyclopropanes and styrylmalonates with various aldehydes, as well as some other transformations with different substrates.
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