Abstract

A sequential analytical method for the determination of238U,234U,232Th,230Th,228Th,228Ra,226Ra and210Pb in environmental samples was developed. Uranium and thorium isotopes are first chromatographically sepaaated using tri-n-octyl phosphine oxide (TOPO) supported on silica gel. The uranium isotopes are determined by alpha-spectrometry following extraction with TOPO onto a polymeric membrane. Thorium isotopes are co-precipitated with lanthanum fluoride before counting in an alpha spectrometer. Radium isotopes and210Pb are separated by co-precipitation/precipitation with mixed barium/lead sulphate. Radium-226 is determined by gross alpha counting of the final BaSO4 precipitate and228Ra by gross beta counting of the same source. Lead-210 is determined through beta counting of its daughter product210Bi.

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