Development of a Pre-Oxidation Treatment to Improve the Adhesion between Thermal Barrier Coatings and NiCoCrAlY Bond Coatings

Abstract

High-temperature coating systems, consisting of a Rene N5 superalloy, a Ni–23Co–23Cr–19Al–0.2Y (at.%) bond coating (BC), and a yttria (7 wt%)-stabilized zirconia (YSZ) thermal barrier coating (TBC), were thermally cycled to failure for seven different controlled pre-oxidation treatments and one commonly employed industrial pre-oxidation treatment to establish the preferred microstructures of the thermally-grown oxide (TGO) on a NiCoCrAlY bond coating after pre-oxidation. It was found that the failure of the coating system occurred along the TGO/BC interface when the TGO attained a critical thickness, except if a NiAl2O4 spinel layer developed contiguous to the TBC/TGO interface. Then, the coating system failed at a smaller TGO thickness along the NiAl2O4/α-Al2O3 interface. The value for the TGO thickness at failure increased for a larger area fraction of Y-rich oxide pegs at the TGO/BC interface after pre-oxidation. A desired slow-growing oxide layer on the BC surface was promoted when the presence of the oxides NiAl2O4, θ-Al2O3, Y3Al5O12 at the TGO surface after pre-oxidation was avoided. The α-Al2O3 layer, which developed adjacent to the BC upon thermal cycling, grew at a low rate if the initial oxide at the onset of oxidation consisted of θ-Al2O3 instead of α-Al2O3. Based on these results a pre-oxidation treatment is proposed for which the lifetime of the entire coating system during service is enhanced.