Development of a novel strength ductile Mg–7Al–5Zn alloy with high superplasticity processed by hard-plate rolling (HPR)

Abstract

In the present study, the application of hard–plate rolling (HPR) on the hard-to-deform Mg–7Al–5Zn (AZ75) alloy resulted in a homogeneous fine grained (∼6 μm) microstructure, where numerous micron/nano Mg17(Al, Zn)12 precipitates with spherical morphology uniformly dispersed both at grain boundaries and within grain interiors. More importantly, the HPRed AZ75 alloy exhibited superior mechanical properties with a simultaneous high strength and ductility at room temperature, i.e. yield strength (YS) of ∼218 MPa, ultimate tensile strength (UTS) of ∼345 MPa and elongation of ∼19%, which was comparable to the commercial wrought magnesium alloys. According to the contribution from the several strengthening mechanisms estimated by simplified models, the grain boundary strengthening is the predominant mechanism for the high YS of the alloy. The high ductility is benefited from the strong work-hardening capacity resulted from Zn solid solutes and the presence of numerous well-dispersed nanosized precipitates as well as weakened texture. Moreover, the fine grained AZ75 alloy exhibits an optimum superplasticity of ∼615% at 300 °C at 1 × 10−3 s−1. It is attributed to the enhanced grain boundary slip (GBS) promoted by a well maintained fine grain structure resulted from the pining effect by numerous Mg17(Al, Zn)12 particles segregating along grain boundaries during tension. The results will be helpful for the development and processing of high alloying element content Mg alloys with high strength and ductility as well as enhanced formability.