Development of a high temperature high strength Al alloy by addition of small amounts of Sc and Mg to 2219 alloy

Abstract

The paper reports a significant improvement in tensile properties, in particular at 200°C, of commercial 2219 Al alloy by addition of small amounts of Sc (0.8wt%) and Mg (0.45wt%), and employing copper mould suction casting followed by natural ageing and cold rolling. Microstructural examination and measurement of hardness were performed in order to explain the effects of Sc and Mg at each processing step. It is found that the remarkable improvement of room temperature strength occurs due to fine grain size, Al3Sc and Al3(Sc,Zr) dispersoids, GP zones on {100} and {111} planes, and work hardening. On exposure at 200°C, the GP zones transform primarily to θ′ precipitates and a few Ω precipitates. Sc and Mg atoms segregate at the θ′/matrix interface, which suppress the coarsening of θ′ precipitates and make them stable at higher temperatures. Thus, the work reports extremely high 0.2% proof stress of 542MPa at room temperature, 378MPa at 200°C and 495MPa at room temperature after 200h exposure at 200°C accompanied by reasonable ductility. Theoretical yield strength is calculated on the basis of the observed microstructure and is found to be in good agreement with the experimentally obtained value.