Development and Optimization of a Purification Process to Recover <sup>99</sup>Mo from Low-enriched Uranium

Abstract

Supported by the DOE-NNSA Office of Material Management & Minimization (M3), a number of domestic entities are pursuing non-highly enriched uranium (non-HEU) production of 99Mo. As the production technologies of 99Mo pivot toward low-enriched uranium (LEU) or molybdenum targets, new reaction channels and accelerators are being evaluated. Superconducting electron linear accelerators (LINACs) with high-Z converter targets can generate bremsstrahlung photons and neutron fluxes that are capable of inducing photonuclear reactions and LEU fission. A particular advantage of a LINAC is that it does not rely on HEU-fueled reactor cores (which are currently slated for LEU conversion) and can operate on an almost continuous basis. Regarding the chemical purification of 99Mo from irradiated uranium targets under acidic digestion, there exists a procedure known as Cintichem or modifications thereof with respect to LEU (LEU Modified Cintichem process, LMC). The process relies on a number of selective precipitation steps and column chromatography to purify Mo. It is important to note that LMC prescribes the addition of stable Mo to carry 99Mo on alpha benzoin oxime, which reduces the specific activity of 99Mo. This is especially important for processing 99Mo batches with lower activities (~33 Ci of 99Mo per batch).