Development and investigation of novel antifouling cellulose acetate ultrafiltration membrane based on dopamine modification

Abstract

In this contribution, a novel cellulose acetate modified with dopamine (CA-DA) membrane material was designed and prepared by a two-step route consist of chlorination and further substitution reactions. The chemical structure of the prepared CA-DA material was determined by FTIR and 1H NMR, respectively. The CA-DA ultrafiltration membrane was subsequently fabricated by the scalable phase inversion process. Compared with cellulose acetate membrane as the control sample, the introduction of dopamine improved the porosity, pore size and hydrophilicity of the CA-DA membrane, which was helpful to the water permeability (181.2 L/m2h) without obviously affecting the protein rejection (93.5%). According to the static protein adsorption and dynamic cycle ultrafiltration experiments, the CA-DA membrane displayed persistent antifouling performance, which was verified by flux recovery ratio, flux decline ratio and filtration resistance. Moreover, the water flux recovery ratio of the CA-DA membrane was retained at 97.3% after three-cycles of BSA solution filtration, which was much higher than that of the reference CA membrane. This new approach provided a long life and excellent ultrafiltration performance for polymer-based membranes, which has potential application prospects in the field of separation process.