Abstract

AbstractWe describe here the development and structural characterization of a new type of mesoionic 1,3‐dipole, which can be generated in the one‐step reaction of imines with pyridine‐ or quinoline‐based acid chlorides. Coupling the formation of these dipoles with alkyne cycloaddition can open a general and modular route to synthesize indolizines from combinations of available and diversifiable building blocks.

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