Development and Characterization of Nano-Ink from Silicon Carbide/Multi-Walled Carbon Nanotubes/Synthesized Silver Nanoparticles for Non-Enzymatic Paraoxon Residuals Detection.

Abstract

The ongoing advancement in the synthesis of new nanomaterials has accelerated the rapid development of non-enzymatic pesticide sensors based on electrochemical platforms. This study aims to develop and characterize Nano-ink for applying organophosphorus pesticides using paraoxon residue detection. Multi-walled carbon nanotubes, silicon carbide, and silver nanoparticles were used to create Nano-ink using a green synthesis process in 1:1:0, 1:1:0.5, and 1:1:1 ratios, respectively. These composites were combined with chitosan of varying molecular weights, which served as a stabilizing glue to keep the Nano-ink employed in a functioning electrode stable. By using X-ray powder diffraction, Raman spectroscopy, energy dispersive X-ray spectroscopy, and a field emission scanning electron microscope, researchers were able to examine the crystallinity, element composition, and surface morphology of Nano-ink. The performance of the proposed imprinted working electrode Nano-ink was investigated using cyclic voltammetry and differential pulse voltammetry techniques. The Cyclic voltammogram of Ag NPs/chitosan (medium, 50 mg) illustrated high current responses and favorable conditions of the Nano-ink modified electrode. Under the optimized conditions, the reduction currents of paraoxon using the DPV techniques demonstrated a linear reaction ranging between 0.001 and 1.0 µg/mL (R2 = 0.9959) with a limit of detection of 0.0038 µg/mL and a limit of quantitation of 0.011 µg/mL. It was concluded that the fabricated Nano-ink showed good electrochemical activity for non-enzymatic paraoxon sensing.