DEVELOPMENT AND ASSESSMENT OF AN ACIDIFICATION CALCULATOR FOR IRRIGATION WATER ALKALINITY REGULATION

Abstract

Excessive alkalinity in greenhouse irrigation water can increase substrate solution pH, resulting in reduced micronutrient availability for plants. A spreadsheet was designed to offer a quick and practical method for calculating: 1) amount of nitric, phosphoric, and sulfuric acid required to achieve an endpoint alkalinity or pH in irrigation water; 2) the amount of nutrients added by the acid addition; and 3) acid costs. It calculates both pH and alkalinity of irrigation water after acidification, regardless of the endpoint selected. The spreadsheet accounts for the pH-dependent reaction that determines the relative percentage of each of the carbonate species—carbonates (CO 2–3), bicarbonates (HCO–3), and carbonic acid (H2CO3)—present in the solution. In addition, the acidification calculations account for the dissociation characteristics of the acid selected to neutralize the alkalinity. The spreadsheet was validated with six water sources from Indiana and North Carolina. Alkalinity neutralization was achieved within an acceptable range (greatest deviation from predicted pH was 0.16 units; greatest deviation from predicted residual alkalinity was 0.21 meq·liter–1) for both target endpoint pHs and endpoint alkalinity concentrations. The mathematical model used in the spreadsheet development provides a chemical basis for acidification and provides results useful for making grower recommendations for acid additions to irrigation water for alkalinity neutralization.