Abstract

This paper reviews the features of alloy components, structure and mechanical properties, physical and chemical properties of metastable Al-based alloys developed by use of various liquid or vapor quenching-induced phases such as amorphous, quasicrystalline, nanocrystalline, nanocomposite, supersaturated solid solution and structure gradient phases. As advantages of the metastable Al-based alloys, one can exemplify a high tensile strength of 1500 MPa for amorphous alloys, high elevated temperature strength of 364 MPa at 573 K for nanoquasicrystalline alloys, high strength of 1000 MPa at room temperature and 520 MPa at 473 K for nanocrystalline alloys, relatively high strength of 596 MPa with large elongation of 16% for nanocomposite alloys and high strength of 900 MPa and distinct elongation of 5% for supersaturated fcc-Al solid solution. These highly functional properties, which have not been obtained for conventional crystalline Al-based alloys, have enabled the commercialization of metastable Al-based alloys as structural, machinery and sporting goods materials. Owing to the significant increase of various fundamental properties caused by the essential differences in the structures, the engineering importance of the metastable Al-based alloys is expected to increase steadily in the future low carbon and nature harmonious society.

Highlights

  • Background and ObjectivesIn recent years, there has been a strong demand of developing advanced structural materials with functional properties such as high specific strength, high elevated temperature specific strength, high fatigue specific strength, low corrosion loss and low wear loss

  • When we focus on the strengthening caused by metastable phases, the effect is due to the combination of solid solution + ultra-high density of defects for amorphous phase and dispersion + grain size refinement + segregation for nanocrystalline phase

  • We have developed metastable Al-based alloys consisting of amorphous, nanocrystalline and nanoquasicrystalline phases

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Summary

Background and Objectives

There has been a strong demand of developing advanced structural materials with functional properties such as high specific strength, high elevated temperature specific strength, high fatigue specific strength, low corrosion loss and low wear loss. By utilizing the combined strengthening mechanisms of these metastable phases, we have tried to prepare novel Al-based alloys with the high tensile strength exceeding 1500 MPa at room temperature, high elevated temperature strength above 500 MPa at 573 K, high rotating beam fatigue strength above 400 MPa at 107 cycles, high elevated temperature fatigue strength above 100 MPa at 673 K after 106 cycles and high corrosion resistance below 20 mm/year in 0.25 M NaOH aqueous solution at 293 K These Al-based alloys have been requested to exhibit a low wear loss, low coefficient of thermal expansion and low material density etc. This paper presents the review of the development achievements of metastable Al-based alloys obtained in our group on the basis of the above-described backgrounds and objectives

Al-based Amorphous Alloys
Bulk Glassy Alloys
Al-based Nanocrystalline Alloys
Al-based Nanocomposite Alloys
Al-based Alloys Reinforced with Bulk Glassy Alloys
Vapor-deposited Al-based Alloys
Structure Gradient Al-based Alloys
10. Applications
Findings
11. Conclusions
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