Abstract
The fate of semivolatile organic compounds in the atmosphere is largely dependent on their partitioning between the gas phase and sorption to particulate matter. Since real atmospheres have been shown to deviate significantly from gas−particle equilibrium under certain conditions, dynamic mass transfer models are needed to accurately predict partitioning. In this work, a dual-impedance radial diffusion model is presented that is able to simulate the partitioning of deuterated fluoranthene in wood and diesel soot atmospheres generated in a large outdoor Teflon film chamber. It is shown that the dual-impedance model produces significantly better fits to experimental results than a one-layer model and that surface mass transfer is not rate limiting in these systems. The sensitivity of optimized apparent diffusion coefficients to key input parameters is also explored. This work lays the foundation for incorporating dynamic gas−particle partitioning models into larger atmospheric models, such as urban airshed ...
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