Developing of N-(4-methylpyrimidine-2-yl)methacrylamide Langmuir-Blodgett thin film chemical sensor via quartz crystal microbalance technique.

Abstract

In the present work, the characterization and gas sensing properties of newly synthesized N-(4-methylpyrimidine-2-yl)methacrylamide (N-MPMA) monomer Langmuir-Blodgett (LB) thin films were investigated. The UV-visible spectroscopy, quartz crystal microbalance (QCM), and atomic force microscopy were utilized to characterize N-MPMA LB thin films. The surface behavior of N-MPMA monolayer was stable and allowed an effective transfer at a surface pressure of 14 mN/m. The mass change/unit area value of the N-MPMA LB thin film deposited quartz crystal surfaces was investigated. The amount of N-MPMA LB thin film deposited on the substrate for bilayer was calculated as 228.72 ng (86.31 ng/mm2 ) and 12.5 Hz frequency shift was observed for each layer of the N-MPMA film. The kinetic responses of N-MPMA LB film against chloroform, dichloromethane, benzene, and toluene were measured via QCM system at room temperature. N-MPMA QCM sensor results displayed that chloroform has the largest frequency shifts compared with the other vapors used in the present work and these results can be illuminating in terms of physical properties of organic vapors.