Abstract
Abstract The deuterium and chlorine nuclear quadrupole coupling constants have been determined for both of the chlorine isotopomers of deuterochloroacetylene (DCCC1), along with the rotational, centrifugal distortion, and chlorine spin-rotation coupling constants. The values are B = 5186.97631 (22) MHz, DJ= 1.13(2) kHz, eQq(Cl)= -79.7358(19) MHz, cI(Cl) = 1.10(31)kHz, and eQq(D) = 207.0(28)kHz for DCCCl-35, and B = 5084.17839(30) MHz, DJ = 0.99(2) kHz, eQq(Cl)= -62.8451(27) MHz, cI(CI) = 0.76(43) kHz, and eQq(D) = 205.8(39)kHz for DCCCl-37.
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