Abstract
Sodium (2-2H2)valerate has been obtained by exchange technique and the kinetic parameters characterizing the oxidation of both sodium valerate of normal isotopic composition and sodium α,α-dideuteriovalerate with manganate in 3M aqueous NaOH solutions have been determined. A discussion of the kinetic deuterium isotope effect observed in the oxidation of CH3CH2CH2CD2COONa is given.
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