Abstract
AbstractThe complete set of deuterium‐induced intrinsic13C NMR isotope shifts,nΔ(13C), for norbornane have been determined from the isotopomeric monodeuteriated systems, and the results are discussed with respect to structure. No correlation is found between1Δ values and thescharacter of the CD bond hybrid. For vicinal isotope effects, however, a quantitative correlation with the dihedral angles of the intervening13C‐CCD bond fragment can be formulated: |3Δ(13C) | (ppb) = 2.2 + [7.3 × 10−3(ϕ −117.8)2]Negative3Δ values are found for bonding pathways in the five‐membered ring partial structure with anantiarrangement of the CCCD bond fragment.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
