Abstract
The hydrogen–deuterium exchange reaction was performed for hydrogenation of D5-1-pentene (4,4,5,5,5) under realistic cobalt Fischer–Tropsch synthesis conditions. In the presence of CO, the added deutero-1-pentene did not show any significant H/D exchange but a step-wise H/D exchange occurs when CO was replaced with N2. The inhibition effects of CO and other FT products on H/D exchange of D5-1-pentene and a pressure dependency effect on H/D exchange are observed.
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