Detonation performance experiments and modeling for the DAAF-based high explosive PBX 9701

Abstract

Abstract Detonation performance experiments and modeling are reported for the explosive PBX 9701, which is composed of 97% 3,3’-diamino-4,4’-azoxyfurazan (DAAF) and 3% vinylidene fluoride-chlorotrifluoroethylene copolymer (Kel-F 800) binder by weight. PBX 9701 is a newly developed reduced-sensitivity explosive with increased performance relative to the triaminotrinitrobenzene or TATB-based PBX 9502 while still retaining low sensitivity to mechanical insult. The first detonation performance measurements for this formulation are presented, including fron curvature rate sticks and cylinder expansion test data. Prior shock initiation data is also reviewed. These data are used to develop programmed burn (PB) and reactive burn (RB) calibrations for existing, commonly used, performance models which allow engineering calculations with PBX 9701. The calibration process involves several enhancements relative to conventional approaches, including the use of an analytical scaling correlation to speed the equation of state (EOS) calibration process. It uses a PB hydrocode-based approach and development of a new methodology to improve the consistency between the PB and RB model calibrations and associated calculations. This link is achieved by populating the RB products EOS in direct reference to the PB release isentrope and Chapman-Jouguet state and in calibrating the timing components of each model using an equivalent procedure, all in order to facilitate comparison between the two modeling approaches. Overall, PBX 9701 is seen to exhibit improved performance relative to insensitive explosives, with a trinitrotoluene (TNT) equivalence of 1.24. The detonation performance properties are found to be well captured by existing models.