Determining the optimum concentration of multiwalled carbon nanotubes as filtrate loss additive in field-applicable mud systems

Abstract

In a bid to combat fluid loss in muds where the effects of high downhole temperatures have pronounced effects on conventional fluid loss additives, several materials have over time been evaluated. One of such materials is the multiwalled carbon nanotubes (MWCNTs). Most studies in the literature limit the scope of their investigation to how the MWCNT affects mud rheology when added in minute concentrations (0.01–1 ppb). In this study, however, the performance of high concentrations (0.5–3 ppb) of multiwall carbon nanotubes as fluid loss control additives in field-applicable mud systems was put to the test. The essence was to establish an optimal concentration useful for field applications. The degree to which the introduction of varying concentrations of the MWCNT altered the muds capacity to control filter loss was the cardinal areas evaluated. The following are the major outcomes of the experimental study: The plastic viscosity, the yield point and the gel strengths showed a progressive increase as the concentration of the MWCNT in the mud increased for both the water- and oil-based muds. However, an optimum concentration of 2 ppb was observed for the water-based mud. For the filter loss tests on the oil-based mud, the results indicate that low concentrations (0.5 ppb) of the MWCNT led to high filter loss volumes (15 ml), but an increase up to 2.5 ppb reduced the margin of the filter loss volume by 52% (7 ml) from the initial value and a 50% decrease for the standard case. In the case of the water-based mud, equivalent amounts of MWCNT recorded less fluid loss than the standard. A moderately hard and firm cake was reported for all concentrations of the standard and MWCNT for the water- and oil-based muds; however, their cake thickness values were 2 mm and 1 mm for the water- and the oil-based muds, respectively.