Determining the key factors of nonradical pathway in activation of persulfate by metal-biochar nanocomposites for bisphenol A degradation

Abstract

• The growth processes of metal-biochar nanocomposites were verified. • The k obs of nonradical pathway was much higher than that of radical pathway. • The key factors determining the activity of nonradical pathway were elucidated. • Nonradical degradation pathway of BPA were proposed and verified the intermediate products. In this study, three types of metal-biochar nanocomposites (CuO/BC, Fe 3 O 4 /BC and ZnO/BC) were synthesized as the catalysts to activate sodium persulfate (PS) for the degradation of bisphenol A (BPA). The results showed that nonradical pathway was the dominant reaction which was based on electron transfer intermediates in the CuO/BC-PS system ( k obs ca. 0.0607 min −1 ) that consumed a small amount of PS (0.17 mM) for the mineralization of all BPA. Meanwhile, the higher k obs would be obtained when contained scavengers, verifying that the generation of intermediates were accompanied by the side reaction (CuO/BC reacted with PS and water to generate OH) in the CuO/BC-PS system. However, OH and SO 4 − were the dominant radicals in the Fe 3 O 4 /BC-PS system (without scavengers, k obs ca. 0.0037 min −1 ). Besides, OH was the main radical in the ZnO/BC-PS system (without scavengers, k obs ca. 0.0046 min −1 ). The mechanism was summarized below: PS effectively bond to unsaturated bonds (i.e., C O lactones) and aromatic structures in the nanocomposites for the generation of the electron transfer intermediates, in which the stabilities of intermediates and the electron transfer capacities of nanocomposites themselves played the critical roles. In addition, nonradical degradation pathway of BPA was proposed, and could give a new insight into metal-carbon nanocomposites activating PS via nonradical pathway.