Abstract
Ten ruthenium pincer complexes were evaluated as catalysts for the hydrodeoxygenation (HDO) reaction on a lignin monomer surrogate, vanillyl alcohol. Four of these complexes are reported herein with the synthesis and full characterization data for all and single-crystal X-ray diffraction data for three complexes bearing OH/O–, NMe2, and Me substituents on the pincer. A systematic study of these CNC pincer complexes revealed that the π-donor substituent on the pyridine ring plays a key role in enhancing the yield of the desired deoxygenated product. While OMe, OH, and NMe2 are all effective as π-donor substituents on the central pyridine ring in the pincer, the highest conversion to products and the best selectivity was observed with OH substituents and added sodium carbonate as a base. Base serves to deprotonate the OH group and form 1O- as observed spectroscopically. Furthermore, efforts to use other catalysts have revealed that free or labile sites are needed on the ruthenium center and an electronicall...
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have