Abstract

Suitable procedures for the determination of diode parameters of illuminated and dark current density-voltage ( j - V ) curves of solar cells are investigated. Within these procedures we avoid misinterpretations by the commonly used shifting approximation which assumes a voltage-independent photo carrier collection. To this end, the voltage-dependent collection efficiency is determined by j - V measurements under incremental illumination. After that, illuminated curves can be converted into dark curves taking the voltage-dependent photo current density into account. The converted dark curve next is consigned into a program that numerically solves the implicit equation of the current density and derives the diode parameters by means of a weighted least-squares minimization. Only if fluctuations of the illumination are noticeably high this procedure cannot be used, since the converted dark curve also reveals a high noise level. Then, the determination of diode parameters is performed stepwise with the help of commonly used methods.

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