Determination of uranium concentration in an ore sample using laser-induced breakdown spectroscopy

Abstract

Laser-induced breakdown spectroscopy (LIBS) has been recognized as a promising technique for analyzing sensitive nuclear materials such as uranium, plutonium, and curium in a high-radiation environment, especially since the implementation of IAEA (International Atomic Energy Agency) safeguards. The uranium spectra of ore samples were quantitatively analyzed prior to analyzing sensitive materials in the nuclear industry. The purpose of this experiment is to extract quantitative information about the uranium in a uranium ore using a standard addition approach. The uranium ore samples containing different concentrations of U were prepared by mixing raw ore powder with natural uranium oxide powders. Calibration sets of 0.2, 0.4, 0.6, 0.8 and 1.0wt.% uranium concentrations within the uranium ore sample were achieved. A pulsed and Q-switched Nd:YAG laser at a wavelength of 532nm was used as a light source. An echelle spectrometer that covers a 190–420nm wavelength range is used to generate a calibration curve and determine the detection limit of uranium in the ore matrix. The neutral atomic-emission peak at a wavelength of 356.659nm indicated a detection limit of ~158ppm for uranium, and the uranium concentration was determined in a raw ore sample that has an unknown quantity of uranium.