Abstract

Difficulties encountered in the determinations of various metals (Cd, Pb, Cu, Fe, Cr, Ni, Co, Zn, Mn) in the graphite furnace are investigated. The most serious is the inconsistency often observed below the upper linear calibration limit. Because of that, and also to avoid the extra work and contamination resulting from dilution, formulae are given that afford a precise way of estimating the concentration within a range 5 to 25 times wider than the linear calibration range. The same computing technique may be employed with equal success when a flame is used, again avoiding dilution.

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