Determination of time zero in high strength concrete containing superabsorbent polymer and nano-silica

Abstract

The autogenous shrinkage is a phenomenon that occurs due to the appearance of tensile stresses in capillary pores. Inherent in the hydration process, not depending on external interference. In high strength concrete, autogenous shrinkage is most pronounced, due to the refinement of microstructure, the high cement content, presence of mineral addictions and low water/cement ratio, which interfere in the transport of water curing. In this context, Superabsorbent polymers (SAP) stand out for their ability to reduce or eliminate the autogenous shrinkage, because they absorb large amounts of water, which is subsequently released into the matrix, avoiding self-desiccation and the onset of tensile stresses (internal curing). However, studies show that SAP can reduce the mechanical strength, which can be compensated by addiction of Nano-silica (NS). In this paper, the effect of these additions in Time Zero (T0) was evaluated. T0 determines the time at which the material starts to behave as a solid, with the development of a rigid mineral skeleton to oppose the volumetric variations that occurs in the paste, which can lead to cracking, compromising esthetics, durability, and structures safety. The ultrasonic pulse velocity test performed the T0, which measures the velocity of propagation of an ultrasonic wave through the material and is taken as the time when a sudden change occurs at this velocity. Nine blends were made containing SAP and NS, where it was found that SAP addition increases the T0 (up to 11%), while NS decrease its value (in 55%).