Abstract
The molecular organization of ethylene copolymers with perfluorinated ethers is studied by inverse gas chromatography. The thermodynamic parameters of sorption of low-molecular-weight sorbates by the copolymers (the activity coefficient, partial molar mixing values) are calculated in a wide temperature range. Influence of the architecture of copolymer chains on the sorption parameters of their thin films is studied. It is shown that, despite the alternating distribution of monomers along copolymer macrochains, methylene groups form hydrocarbon clusters in a perfluorinated dispersion medium. The microheterogeneous structure of the studied copolymers is responsible for the permeability of copolymer thin films to low-molecular-weight liquid sorbates (both solvents and nonsolvents). It is suggested that the copolymers of this type are promising for use in the field of membrane technologies.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
