Abstract
Gas–liquid chromatographic retention factors have been measured for 42 different organic probes on a 2-methoxyethyl(dimethyl)ethylammonium tris(pentafluoroethyl)trifluorophosphate, ([MeoeM2EAm]+[FAP]–), stationary phase capillary column at 323 and 353 K. The measured retention factors were combined with published gas-to-liquid partition coefficient data for solutes dissolved in ([MeoeM2EAm]+[FAP]–) and with published gas-to-water partition coefficient data to yield 107 gas-to-anhydrous ionic liquid and 105 water-to-anhydrous ionic liquid partition coefficients. Abraham model correlations for describing solute transfer into ([MeoeM2EAm]+[FAP]–) were derived from the three sets of experimental partition coefficient data. The derived correlations back-calculated the experimental gas-to-([MeoeM2EAm]+[FAP]–) and water-to-([MeoeM2EAm]+[FAP]–) partition coefficient data to within 0.13 and 0.15 log units, respectively.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
