Abstract
Cyclic voltammetry (CV) of LiNi 0.8Co 0.2O 2/Li half-cell and mesocarbon microbead (MCMB)/Li half-cell are studied at very low scan rates. The thermal behaviors of these two half-cells and LiNi 0.8Co 0.2O 2/MCMB full-cell cycled at different current levels are studied with electrochemical-microcalorimeter technique in terms of reversible and irreversible heat generation. The calculated results show excellent agreement with the experimental data at low and moderate current levels (≤C/4). The quantitative heat contributions of the cathode and anode to the overall cell heat generation are also determined.
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