Abstract
Abstract In the extraction of divalent Cu, Zn and Cd from HCl solutions by trioctylmethylammohium chloride in various organic solvents, the heat change associated with the uptake of metal has been examined by using a twin type isoperibol calorimeter. As a result, it is found that the heat change detected is interpreted as the summation over the change in enthalpies for the relevant steps to the extraction, taking the change in enthalpy obtained from the temperature-dependence of the distribution coefficient into account, and that the distribution of metal between aqueous and organic phases can be explained by assuming a regular solution.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callSimilar Papers
More From: Thermochimica Acta
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
