Abstract
A measurement of the fine-structure properties of the atomic chlorine $2p$ subshell has been carried out using electron spectrometry in conjunction with synchrotron radiation. We observe eight of the ten photopeaks predicted for this open-shell atom. Binding energies, relative intensities, and angular distribution parameters are reported for an incident photon energy of 245 eV. Experimental binding energies and intensities are in reasonable agreement with our calculations using a Slater-Condon superposition-of-configuration method.
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