Abstract
The nature of the coefficients in the linear dependence of a partial molar free energy of solution on a retention index value for all substances analyzed on a stationary phase has been ascertained. A simple procedure for estimating the difference of intermolecular interaction energies after replacement of n-alkyl radicals with isoalkyl or unsaturated radicals in aliphatic sulphides and disulphides has been evaluated. Variations of intermolecular interaction energies of the functional group in metameric thiatridecanes with the displacement of the S atom into the carbon chain have been determined.
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