Abstract
Abstract The photolysis of RhCH3(ttp) and RhCH3(tmp) (ttp = 5,10,15,20-tetratolylporphyrin, tmp = 5,10,15,20-tetramesitylporphyrin) was studied in methanol at ambient temperature: the quantum yields for photolysis were determined to be 0.51 and 0.54, respectively, and the Rh–C bond dissociation energies (227 and 219 kJ mol−1, respectively) were measured by photoacoustic calorimetry, which were larger than those of Co–C bond.
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