Determination of recovery rates of adsorbents for sampling very volatile organic compounds (C1C6) in dry and humid air in the sub-ppb range by use of thermal desorption gas chromatography-mass spectrometry.

Abstract

The reliable measurement of very volatile organic compounds (VVOC) in indoor air by use of thermal desorption gas chromatography (TD-GC) in order to include them into evaluation schemes for building products even nowadays is a great challenge. For capturing these small molecules with carbon numbers ranging from C1C6, strong adsorbents are needed. In the present study, recovery rates of nine suitable adsorbents of the groups of porous polymers, graphitised carbon blacks (GCB) and carbon molecular sieves (CMS) are tested against a complex test gas standard containing 29 VVOC. By consideration of the recovery and the relative humidity (50%RH), combinations of the GCB Carbograph5TD, the two CMS Carboxen1003 and CarbosieveSII as well as the porous polymer Tenax®GR were identified to be potentially suitable for sampling the majority of the VVOC out of the gas mix. The results reveal a better performance of the adsorbents in combination than being used alone, particularly under humid sampling conditions. The recovery rates of the chosen compounds on each adsorbent should be in the range of 80-120%.