Abstract
The low pressure association reactions for the proton bound dimers of acetonitrile, acetone, dimethyl ether and diethyl ether have been studied using Fourier transform-ion cyclotron resonance spectrometry. Values for the rate constants for the unimolecular decomposition and radiative stabilization reactions of the intermediate proton bound dimer are determined. Trends of molecular size and number of normal modes are examined for unimolecular lifetimes of the association intermediate. No apparent trends are observed to allow the prediction of radiative stabilization lifetimes.
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