Determination of Polychlorinated Biphenyls in Water Samples Using a Needle Trap Device Combined with Gas Chromatography

Abstract

In this study, a fiber-packed needle trap device (NTD) was developed by packing heat-resistant fibers with a polyethylene glycol sol-gel coating into a 21-gauge, stainless steel needle. The polyethylene glycol sol-gel coating has numerous advantages, including uniform roughness and a large specific surface area. The prepared NTD was used for headspace extraction of five polychlorinated biphenyls (PCBs) in water samples, determined by gas chromatography with a flame ionization detector (GC-FID). The main experimental parameters, including the extraction and desorption conditions, ionic strength, and fiber bundles, were investigated to improve the extraction efficiency. After optimization, satisfactory linearity (r > 0.99) in the concentration range of 0.02–500 μg/L was obtained, and the enrichment factor of NTD for the five PCBs was between 1150 and 9537 times. The limit of detection (S/N = 3) of five PCBs were measured in ranges of 0.0021–0.01 μg/L. Furthermore, the fiber-packed NTD has excellent durability, and can be reused for 60 cycles. After being stored at room temperature for three days, the storage ability of the NTD had a loss of PCBs less than 10%, and the relative standard deviation (RSD) was less than 10%. When analyzing the PCBs in real water samples, good accuracies (spiked recoveries were in the range of 92.19–98.56%) and precision (the RSD was lower than 12.8%) was obtained.